The tournament, played at the Hurlingham Club in London, has secured Murray as its headline act.
The world number two, who will play competitively at Queen's Club the week before, said: "I'm really looking forward to being back at the Hurlingham Club. It's the perfect way for me to warm up for Wimbledon - there's always a great atmosphere and the setting is absolutely stunning."
Fellow top-20 stars Jo Wilfried Tsonga, Tommy Haas and Kei Nishikori have also signed up to appear.
Numerous legends will also be on show, including former Wimbledon champions Pat Cash and Goran Ivanisevic.
The BNP Paribas Classic takes place from June 18-22. The Hurlingham Club is situated on the north bank of the Thames in Fulham.